JPS595525B2 - 純粋な塩化アルミニウムの製造方法 - Google Patents
純粋な塩化アルミニウムの製造方法Info
- Publication number
- JPS595525B2 JPS595525B2 JP55064651A JP6465180A JPS595525B2 JP S595525 B2 JPS595525 B2 JP S595525B2 JP 55064651 A JP55064651 A JP 55064651A JP 6465180 A JP6465180 A JP 6465180A JP S595525 B2 JPS595525 B2 JP S595525B2
- Authority
- JP
- Japan
- Prior art keywords
- column
- chloride
- mixture
- temperature
- distillation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 title claims description 114
- 239000000203 mixture Substances 0.000 claims description 40
- 229910001510 metal chloride Inorganic materials 0.000 claims description 37
- 238000004821 distillation Methods 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 16
- 238000005660 chlorination reaction Methods 0.000 claims description 15
- 238000004508 fractional distillation Methods 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 238000000859 sublimation Methods 0.000 claims description 3
- 230000008022 sublimation Effects 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 49
- 239000007789 gas Substances 0.000 description 42
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 32
- 239000005049 silicon tetrachloride Substances 0.000 description 32
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 23
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 23
- 238000010791 quenching Methods 0.000 description 21
- 239000006096 absorbing agent Substances 0.000 description 18
- 238000009835 boiling Methods 0.000 description 12
- 150000001805 chlorine compounds Chemical class 0.000 description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
- 238000000926 separation method Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- 239000004927 clay Substances 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 238000011144 upstream manufacturing Methods 0.000 description 6
- 235000011148 calcium chloride Nutrition 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000008246 gaseous mixture Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 229910001338 liquidmetal Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000004131 Bayer process Methods 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XGIAHMUOCFHQTI-UHFFFAOYSA-N Cl.Cl.Cl.Cl.CC Chemical compound Cl.Cl.Cl.Cl.CC XGIAHMUOCFHQTI-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical class [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- VBFBBEDUJWNHHL-UHFFFAOYSA-N [Cl].[Cl].[Cl].[Cl].[Ti] Chemical compound [Cl].[Cl].[Cl].[Cl].[Ti] VBFBBEDUJWNHHL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- -1 ferric chloride) Chemical compound 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
- B01D3/146—Multiple effect distillation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/08—Compounds containing halogen
- C01B33/107—Halogenated silanes
- C01B33/1071—Tetrachloride, trichlorosilane or silicochloroform, dichlorosilane, monochlorosilane or mixtures thereof
- C01B33/10715—Tetrachloride, trichlorosilane or silicochloroform, dichlorosilane, monochlorosilane or mixtures thereof prepared by reacting chlorine with silicon or a silicon-containing material
- C01B33/10721—Tetrachloride, trichlorosilane or silicochloroform, dichlorosilane, monochlorosilane or mixtures thereof prepared by reacting chlorine with silicon or a silicon-containing material with the preferential formation of tetrachloride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/48—Halides, with or without other cations besides aluminium
- C01F7/56—Chlorides
- C01F7/62—Purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
- C01G1/06—Halides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/02—Halides of titanium
- C01G23/022—Titanium tetrachloride
- C01G23/024—Purification of tetrachloride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/10—Halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4094579A | 1979-05-21 | 1979-05-21 | |
| US40945 | 1979-05-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55158121A JPS55158121A (en) | 1980-12-09 |
| JPS595525B2 true JPS595525B2 (ja) | 1984-02-06 |
Family
ID=21913854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55064651A Expired JPS595525B2 (ja) | 1979-05-21 | 1980-05-15 | 純粋な塩化アルミニウムの製造方法 |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS595525B2 (en]) |
| AU (1) | AU531330B2 (en]) |
| BR (1) | BR8003086A (en]) |
| CA (1) | CA1121982A (en]) |
| FR (1) | FR2457256A1 (en]) |
| GB (1) | GB2049452B (en]) |
| GR (1) | GR67754B (en]) |
| NL (1) | NL8002806A (en]) |
| OA (1) | OA06536A (en]) |
| PL (1) | PL124027B1 (en]) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2514028B1 (fr) * | 1981-10-01 | 1986-05-09 | Pechiney Aluminium | Procede de chloruration selective de melanges d'oxydes metalliques d'origine naturelle ou synthetique |
| US6964728B2 (en) | 2002-05-16 | 2005-11-15 | Mckinnie Bonnie G | Separation process |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2387228A (en) * | 1942-08-10 | 1945-10-23 | Phillips Petroleum Co | Method of purifying anhydrous aluminum chloride |
| US2768070A (en) * | 1953-01-26 | 1956-10-23 | Universal Oil Prod Co | Means for preparing aluminum chloride |
-
1980
- 1980-04-02 AU AU57084/80A patent/AU531330B2/en not_active Ceased
- 1980-04-10 CA CA000349560A patent/CA1121982A/en not_active Expired
- 1980-04-18 FR FR8008780A patent/FR2457256A1/fr active Granted
- 1980-04-23 GB GB8013345A patent/GB2049452B/en not_active Expired
- 1980-04-28 GR GR61803A patent/GR67754B/el unknown
- 1980-05-14 NL NL8002806A patent/NL8002806A/nl not_active Application Discontinuation
- 1980-05-15 JP JP55064651A patent/JPS595525B2/ja not_active Expired
- 1980-05-16 BR BR8003086A patent/BR8003086A/pt unknown
- 1980-05-20 PL PL1980224362A patent/PL124027B1/pl unknown
- 1980-05-21 OA OA57116A patent/OA06536A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB2049452A (en) | 1980-12-31 |
| GB2049452B (en) | 1983-05-18 |
| BR8003086A (pt) | 1980-12-23 |
| JPS55158121A (en) | 1980-12-09 |
| PL124027B1 (en) | 1982-12-31 |
| FR2457256B1 (en]) | 1984-08-24 |
| NL8002806A (nl) | 1980-11-25 |
| PL224362A1 (en]) | 1981-02-13 |
| GR67754B (en]) | 1981-09-18 |
| AU5708480A (en) | 1980-11-27 |
| AU531330B2 (en) | 1983-08-18 |
| CA1121982A (en) | 1982-04-20 |
| OA06536A (fr) | 1981-07-31 |
| FR2457256A1 (fr) | 1980-12-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2533021A (en) | Separating metal halide vapors | |
| JPS61115035A (ja) | 精製１，２‐ジクロルエタンの熱分解による塩化ビニルの製造法 | |
| US2744060A (en) | Process for separating hafnium tetrachloride from zirconium tetrachloride | |
| US2387228A (en) | Method of purifying anhydrous aluminum chloride | |
| US4822932A (en) | Heat recovery in production of vinyl chloride by pyrolysis of dichloroethane | |
| US2594370A (en) | Method of separating metal halides | |
| US3938969A (en) | Purification of aluminum chloride | |
| US4385964A (en) | Method for preventing the undesirable condensation of aluminum chloride in a fractional distillation column | |
| US4035169A (en) | Process for the purification of aluminum chloride | |
| US3109864A (en) | Oxidation of hydrocarbons | |
| CA1049517A (en) | Process for producing finely divided solid cyanuric chloride | |
| JPH11116511A (ja) | １，１，１，２，２−ペンタフルオロエタンの製造方法 | |
| JPS5892626A (ja) | １，２−ジクロルエタンの製法 | |
| US2768070A (en) | Means for preparing aluminum chloride | |
| KR20130124323A (ko) | 실란 정제 공정 및 시스템 | |
| US3758572A (en) | Process for recovering urea from pyrolysis systems | |
| JPS595525B2 (ja) | 純粋な塩化アルミニウムの製造方法 | |
| US3179662A (en) | Purification of cyanuric chloride | |
| US4243650A (en) | Heat and volatized salt recovery from reaction effluent | |
| US3294482A (en) | Process for recovering metal chlorides from gaseous mixtures | |
| JP3247420B2 (ja) | 四塩化チタンの製造方法 | |
| GB1081579A (en) | Method and apparatus for fractional sublimation | |
| US2742977A (en) | Vapors of | |
| CN110540486B (zh) | 一种四氯乙烯生产中副产高沸物的分离系统及分离方法 | |
| US3298933A (en) | Production of ultra-pure phenol by removal from a phenol of high purity of small amounts of chlorine-containing organic impurities |